Issue 7, 2010
From the journal:

CrystEngComm

Novel three-dimensional Ln–Ag 4d–4f heteropentametallic helix-based microporous metal–organic framework with unprecedented (3,4,5,6)-connected topology constructed from isonicotinate ligand†

Zhao-Yang Li,a   Jing-Wei Dai,a   Shan-Tang Yue*a  and  Ying-Liang Liu*b  

* Corresponding authors

a School of Chemistry and Environment, South China Normal University, Guangzhou, P. R. China
E-mail: yuesht@scnu.edu.cn
Fax: +86-20-39310187
Tel: +86-13711179206

b Department of Chemistry, Jinan University, Guangzhou, P. R. China

Abstract

An unprecedented 4d–4f heterometallic helix-based MMOF with a new (3,4,5,6)-connected topology, {[Ln2Ag3(ina)6(ox)0.5(μ2-OH2)(H2O)2.5]·1.5H2O·2NO3}n, is presented, which consists of coaxial bi-strand helices interconnected by the carboxyl groups of the ligands. Selective anion-exchange functions of the title compound containing NO3− counter anions were identified.

Graphical abstract: Novel three-dimensional Ln–Ag 4d–4f heteropentametallic helix-based microporous metal–organic framework with unprecedented (3,4,5,6)-connected topology constructed from isonicotinate ligand

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Article information

DOI
https://doi.org/10.1039/C000058B
Article type
Communication
Submitted
06 Jan 2010
Accepted
01 Mar 2010
First published
05 Mar 2010

CrystEngComm, 2010,12, 2014-2017

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Novel three-dimensional Ln–Ag 4d–4f heteropentametallic helix-based microporous metal–organic framework with unprecedented (3,4,5,6)-connected topology constructed from isonicotinate ligand

Z. Li, J. Dai, S. Yue and Y. Liu, CrystEngComm, 2010, 12, 2014 DOI: 10.1039/C000058B

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