Issue 6, 2010
From the journal:

CrystEngComm

A 3D organic–inorganic network constructed from an Anderson-type polyoxometalate anion, a copper complex and a tetrameric [Na4(H2O)14]4+cluster†,‡

Suzhi Li,a   Pengtao Ma,a   Jingping Wang,*a   Yuanyuan Guo,a   Haizhu Niu,a   Junwei Zhaoa  and  Jingyang Niu*a  

* Corresponding authors

a Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan, P. R. China
E-mail: jpwang@henu.edu.cn, jyniu@henu.edu.cn
Fax: (+86) 378-3886876

Abstract

A rare three-dimensional organic–inorganic compound based on the Anderson-type polyoxometalate anion, [Na4(H2O)14Cu(PDA)2]H[Al(OH)6Mo6O18]·5H2O (H2PDA = pyrazine-2,3-dicarboxylic acid) (1) has been synthesized, in which each Anderson polyoxoanion [Al(OH)6Mo6O18]3− acts as a decadentate ligand, connecting four tetrameric [Na4(H2O)14]4+ clusters and two [Cu(PDA)2]2− coordination ions through terminal oxygen atoms.

Graphical abstract: A 3D organic–inorganic network constructed from an Anderson-type polyoxometalate anion, a copper complex and a tetrameric [Na4(H2O)14]4+ cluster,

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Article information

DOI
https://doi.org/10.1039/B924394A
Article type
Communication
Submitted
20 Nov 2009
Accepted
27 Jan 2010
First published
19 Feb 2010

CrystEngComm, 2010,12, 1718-1721

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A 3D organic–inorganic network constructed from an Anderson-type polyoxometalate anion, a copper complex and a tetrameric [Na4(H2O)14]4+ cluster,

S. Li, P. Ma, J. Wang, Y. Guo, H. Niu, J. Zhao and J. Niu, CrystEngComm, 2010, 12, 1718 DOI: 10.1039/B924394A

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