(C2H8N)9[Eu5(SO4)12]·2H2O: the first europium sulfate open-framework containing two kinds of intersecting extra-large 20-membered ring channels

Lei Zheng; Yan Xu; Xiaoliang Zhang; Zhibin Zhang; Dunru Zhu; Su Chen; S. P. Elangovan

doi:10.1039/B919703F

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(C₂H₈N)₉[Eu₅(SO₄)₁₂]·2H₂O: the first europium sulfate open-framework containing two kinds of intersecting extra-large 20-membered ring channels†

Lei Zheng,^a Yan Xu,*^a Xiaoliang Zhang,^a Zhibin Zhang,^a Dunru Zhu,^a Su Chen^a and S. P. Elangovan^b

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* Corresponding authors

^a State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing, China
E-mail: yanxu@njut.edu.cn

^b Department of Science & Technology, Nippon Chemical Industrial Co. Ltd., 9-11-1 Kameido, Koto-ku, Tokyo, Japan

Abstract

A novel organic amine templated europium sulfate [(C₂NH₈)₉][Eu₅(SO₄)₁₂]·2H₂O 1 has been synthesized using a small organic amine (dimethylamine) as a structural directing agent (SDA). Crystal structural analysis indicates that the inorganic framework of 1 contains two kinds of extra-large 20MR channels.

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Article information

DOI: https://doi.org/10.1039/B919703F
Article type: Communication
Submitted: 21 Sep 2009
Accepted: 02 Oct 2009
First published: 15 Oct 2009

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CrystEngComm, 2010,12, 694-696

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(C₂H₈N)₉[Eu₅(SO₄)₁₂]·2H₂O: the first europium sulfate open-framework containing two kinds of intersecting extra-large 20-membered ring channels

L. Zheng, Y. Xu, X. Zhang, Z. Zhang, D. Zhu, S. Chen and S. P. Elangovan, CrystEngComm, 2010, 12, 694 DOI: 10.1039/B919703F

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