Issue 6, 2010
From the journal:

CrystEngComm

A chiral diamondoid 3D lanthanum metal–organic framework displaying blue-greenish long lifetime photoluminescence emission†

A. Rodríguez-Diéguez,*a   A. Salinas-Castillo,b   A. Sironi,c   J. M. Secod  and  E. Colacioa  

* Corresponding authors

a Departamento de Química Inorgánica, Universidad de Granada, Granada 18071, Spain
E-mail: antonio5@ugr.es
Tel: +34 958 243 236

b Instituto de Biología Molecular y Celular, Universidad Miguel Hernández, Elche 03202, Spain

c Dipartimento di Chimica Strutturale e Stereochimica Inorganica, Università degli Studi di Milano, Milano, Italy

d Departamento de Química Aplicada, Facultad de Ciencias de San Sebastián, Universidad del País Vasco, Paseo Manuel Lardizábal, San Sebastián 20008, Spain

Abstract

The compound [La(pmtz)(TzC)(H2O)3](H2O) (pmtz = 5-(pyrimidyl)-tetrazolato, TzC = 5-carboxylato-tetrazolato) has been prepared under hydrothermal conditions and exhibits a 3D diamondoid network. This three-dimensional metal–organic framework has channels with hosted water molecules inside and shows an intense blue-greenish long lifetime photoluminescence emission at room temperature in the solid state with two lifetime decay values of 0.26 and 27 ms.

Graphical abstract: A chiral diamondoid 3D lanthanum metal–organic framework displaying blue-greenish long lifetime photoluminescence emission

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Article information

DOI
https://doi.org/10.1039/B919243C
Article type
Paper
Submitted
16 Sep 2009
Accepted
16 Jan 2010
First published
01 Feb 2010

CrystEngComm, 2010,12, 1876-1879

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A chiral diamondoid 3D lanthanum metal–organic framework displaying blue-greenish long lifetime photoluminescence emission

A. Rodríguez-Diéguez, A. Salinas-Castillo, A. Sironi, J. M. Seco and E. Colacio, CrystEngComm, 2010, 12, 1876 DOI: 10.1039/B919243C

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