Issue 4, 2010
From the journal:

CrystEngComm

Thiacalix[4]arene–rubidiumassembly: supramolecular architecture based on alkali metal coordination and cation–π interactions†

Manabu Yamada,a   Yoshifumi Shimakawa,a   Yoshihiko Kondoab  and  Fumio Hamada*ab  

* Corresponding authors

a Department of Material-Process and Applied Chemistry for Environments, Faculty of Engineering and Resource Science, Akita University, Akita, Japan
E-mail: hamada@ipc.akita-u.ac.jp
Fax: +81 18 837 0404
Tel: +81 18 889 2440

b Department of Life Science, Faculty of Engineering and Resource Science, Akita University, Akita, Japan

Abstract

Single-crystal X-ray diffraction study of a thiacalix[4]arene complex with a rubidium cation demonstrated in different coordination environments of two thiacalix[4]arene molecular units, η2 and η6 coordination between rubidium cations and thiacalix[4]arene aromatic rings outside of the cavities.

Graphical abstract: Thiacalix[4]arene–rubidium assembly: supramolecular architecture based on alkali metal coordination and cation–π interactions

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Article information

DOI
https://doi.org/10.1039/B916317D
Article type
Paper
Submitted
07 Aug 2009
Accepted
17 Nov 2009
First published
22 Dec 2009

CrystEngComm, 2010,12, 1311-1315

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Thiacalix[4]arene–rubidium assembly: supramolecular architecture based on alkali metal coordination and cation–π interactions

M. Yamada, Y. Shimakawa, Y. Kondo and F. Hamada, CrystEngComm, 2010, 12, 1311 DOI: 10.1039/B916317D

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