Issue 4, 2010
From the journal:

CrystEngComm

Capturing in situ generated NH[double bond, length as m-dash]CH–N[double bond, length as m-dash]NH molecule via the templating synthesis of a 4-connected open Cd(ii) framework†

Jian-Kai Cheng,a   Jian Zhang,a   Pei-Xiu Yin,a   Qi-Pu Lin,a   Zhao-Ji Lia  and  Yuan-Gen Yao*a  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, China
E-mail: yyg@fjirsm.ac.cn
Fax: (+86)-591-83714946

Abstract

An unprecedented in situ generated NH[double bond, length as m-dash]CH–N[double bond, length as m-dash]NH molecule successfully templated the formation of a photoluminescent 4-connected open Cd(II) framework with the umc topology, which first demonstrated the ring-opening reaction from the N,S-containing ligand. The results provide a new templating synthetic route to understand the mechanism of hydro(solvo)thermal in situ ligand synthesis via capturing small in situ generated molecular fragments.

Graphical abstract: Capturing in situ generated NH [[double bond, length as m-dash]] CH–N [[double bond, length as m-dash]] NH molecule via the templating synthesis of a 4-connected open Cd(ii) framework

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Supplementary files

Article information

DOI
https://doi.org/10.1039/B916206B
Article type
Communication
Submitted
06 Aug 2009
Accepted
26 Oct 2009
First published
05 Nov 2009

CrystEngComm, 2010,12, 1024-1026

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Capturing in situ generated NH[double bond, length as m-dash]CH–N[double bond, length as m-dash]NH molecule via the templating synthesis of a 4-connected open Cd(II) framework

J. Cheng, J. Zhang, P. Yin, Q. Lin, Z. Li and Y. Yao, CrystEngComm, 2010, 12, 1024 DOI: 10.1039/B916206B

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