Issue 5, 2010

Different spatial orientations of amide derivatives on anion coordination

Abstract

The N-[2-(4-methoxypheny)-ethyl]-2-(quinolin-8-yl-amino)acetamide is a stretched amide, whose protonated perchlorate salt has a tweezer-like geometry. The self assembly of the salt molecules through weak C–H⋯π and C–H⋯O interactions gives a channel like structure. The crystal structure of two salts of N-quinolin-8-yl-2-(quinolin-8-yloxy)acetamide (II) is determined. The corresponding perchlorate salt arises from di-protonatation of the parent amide derivative, whereas the tetrafluroborate salt formed is a mono-protonated species of the amide derivative II. The di-protonated species has a concave shape but mono-protonated species adopts an S-shaped geometry.

Graphical abstract: Different spatial orientations of amide derivatives on anion coordination

Supplementary files

Article information

Article type
Paper
Submitted
27 Jul 2009
Accepted
08 Dec 2009
First published
11 Jan 2010

CrystEngComm, 2010,12, 1562-1567

Different spatial orientations of amide derivatives on anion coordination

D. Kalita and J. B. Baruah, CrystEngComm, 2010, 12, 1562 DOI: 10.1039/B915230J

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