Issue 2, 2010

Calixarene C8-imidazolium interplay as a design strategy for penetrating organic bi-layers

Abstract

1-Octyl-3-methylimidazolium (C8-mim) cation forms multi-component bi-layers with p-sulfonatocalix[4]arene and phosphonium ions, and aquated lanthanide ions, with the imidazolium head group residing in the calixarene cavity and the terminus of the C8 chain penetrating the adjacent hydrophobic bi-layer which is comprised of calixarenes and phosphonium ions, as part of a porous-like extended structure. Hirshfeld surface analyses reveal the nature of the interactions between the components.

Graphical abstract: Calixarene C8-imidazolium interplay as a design strategy for penetrating organic bi-layers

Supplementary files

Article information

Article type
Paper
Submitted
10 Jul 2009
Accepted
15 Sep 2009
First published
05 Oct 2009

CrystEngComm, 2010,12, 573-578

Calixarene C8-imidazolium interplay as a design strategy for penetrating organic bi-layers

I. Ling, Y. Alias, A. N. Sobolev and C. L. Raston, CrystEngComm, 2010, 12, 573 DOI: 10.1039/B913826A

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