Issue 2, 2010

Lone pair–π vs π–π interactions in 5-fluoro-1-hexyluracil and 1-hexyluracil: a combined crystallographic and computational study

Abstract

The simple substitution of a hydrogen atom by a fluorine atom in 1-hexyluracil has an enormous consequence on the solid state structure due to the increment in the π-acidity of the ring.

Graphical abstract: Lone pair–π vs π–π interactions in 5-fluoro-1-hexyluracil and 1-hexyluracil: a combined crystallographic and computational study

Supplementary files

Article information

Article type
Communication
Submitted
01 Jul 2009
Accepted
28 Sep 2009
First published
07 Oct 2009

CrystEngComm, 2010,12, 362-365

Lone pair–π vs π–π interactions in 5-fluoro-1-hexyluracil and 1-hexyluracil: a combined crystallographic and computational study

M. Barceló-Oliver, C. Estarellas, A. García-Raso, A. Terrón, A. Frontera, D. Quiñonero, E. Molins and P. M. Deyà, CrystEngComm, 2010, 12, 362 DOI: 10.1039/B913111F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements