Issue 2, 2010
From the journal:

CrystEngComm

Pillared cobalt–organic framework with an unprecedented (3,4,6)-connected architecture showing the coexistence of spin canting and long-range magnetic ordering†

Fu-Ping Huang,a   Jin-Lei Tian,a   Dong-Dong Li,a   Gong-Jun Chen,a   Wen Gu,a   Shi-Ping Yan,*a   Xin Liu,a   Dai-Zheng Liaoa  and  Peng Chenga  

* Corresponding authors

a Department of Chemistry, Nankai University, Tianjin, P. R China
E-mail: yansp@nankai.edu.cn
Fax: +86-022-23502779
Tel: +86-022-23505063

Abstract

A novel (3,4,6)-connected 3D porous cobalt–organic framework formulated as {[Co2(Hbidc)2(bpt)2]·7H2O}n (1) (H3bidc = 1H-benzimidazole-5,6-dicarboxylic acid, bpt = 1H-3,5-bis(4-pyridyl)-1,2,4- triazole) has been hydrothermally synthesized and characterized by X-ray diffraction analysis. Compound 1, having a Co-Hbidc layer structure in which the layers are pillared by the bpt spacers in a 3D architecture, exhibits the coexistence of spin-canted weak ferromagnetism with TN = 10 K and long-range magnetic ordering.

Graphical abstract: Pillared cobalt–organic framework with an unprecedented (3,4,6)-connected architecture showing the coexistence of spin canting and long-range magnetic ordering

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Article information

DOI
https://doi.org/10.1039/B911950G
Article type
Paper
Submitted
17 Jun 2009
Accepted
27 Aug 2009
First published
11 Sep 2009

CrystEngComm, 2010,12, 395-400

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Pillared cobalt–organic framework with an unprecedented (3,4,6)-connected architecture showing the coexistence of spin canting and long-range magnetic ordering

F. Huang, J. Tian, D. Li, G. Chen, W. Gu, S. Yan, X. Liu, D. Liao and P. Cheng, CrystEngComm, 2010, 12, 395 DOI: 10.1039/B911950G

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