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Issue 46, 2010
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Complete disassembly of carbon disulfide by a ditantalum complex

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Abstract

The side-on end-on dinitrogen complex [PhP(CH2SiMe2NPh)2Ta](μ-H)2(μ-η21-N2) reacts with CS2 with complete cleavage of both C[double bond, length as m-dash]S double bonds and the formation of [PhP(CH2SiMe2NPh)2Ta](μ-S)2(μ-CH2), which has two bridging sulfides and a bridging methylene unit. Further reaction with H2 produces CH4 and the disulfide complex.

Graphical abstract: Complete disassembly of carbon disulfide by a ditantalum complex

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Article information


Submitted
25 Aug 2010
Accepted
23 Sep 2010
First published
19 Oct 2010

Chem. Commun., 2010,46, 8794-8796
Article type
Communication

Complete disassembly of carbon disulfide by a ditantalum complex

J. Ballmann, A. Yeo, B. A. MacKay, S. V. Rijt, B. O. Patrick and M. D. Fryzuk, Chem. Commun., 2010, 46, 8794
DOI: 10.1039/C0CC03483E

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