Issue 46, 2010
From the journal:

Chemical Communications

Selective reduction of a Pd pincer PCP complex to well-defined Pd(0) species†

Cristóbal Melero,a   Luis M. Martínez-Prieto,a   Pilar Palma,a   Diego del Rio,b   Eleuterio Álvareza  and  Juan Cámpora*a  

* Corresponding authors

a Instituto de Investigaciones Químicas, CSIC-Universidad de Sevilla, c/ Américo Vespucio, 49, 41092, Sevilla, Spain
E-mail: campora@iiq.csic.es
Fax: +34 954460565

b SRI International, 333 Ravenswood Avenue, Menlo Park, CA, USA

Abstract

Well-defined dimeric or polymeric Pd(0) complexes [Pd(μ-iPrPCHP)]n (n = 2 or ∞) containing the bridging ligand α,α′-bis(diisopropylphosphino)-m-xylene (iPrPCHP) are produced under mild conditions when the cyclometallated PCP pincer complex (iPrPCP)Pd–OH reacts with methanol or isopropanol.

Graphical abstract: Selective reduction of a Pd pincer PCP complex to well-defined Pd(0) species

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Article information

DOI
https://doi.org/10.1039/C0CC02972F
Article type
Communication
Submitted
02 Aug 2010
Accepted
20 Sep 2010
First published
21 Oct 2010

Chem. Commun., 2010,46, 8851-8853

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Selective reduction of a Pd pincer PCP complex to well-defined Pd(0) species

C. Melero, L. M. Martínez-Prieto, P. Palma, D. del Rio, E. Álvarez and J. Cámpora, Chem. Commun., 2010, 46, 8851 DOI: 10.1039/C0CC02972F

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