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Issue 42, 2010
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Cooperative spin crossover phenomena in [Fe(NH2trz)3](tosylate)2 nanoparticles

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Abstract

Nanoparticles of the [Fe(NH2trz)3](tosylate)2 spin crossover complex of 3–4 nm size were synthesized and dispersed in a nonionic surfactant. This colloidal system exhibits thermal spin crossover phenomena associated with a virtually first order transition. By thermal treatment the colloidal suspension can be transformed into a fibrous structure forming a gel.

Graphical abstract: Cooperative spin crossover phenomena in [Fe(NH2trz)3](tosylate)2 nanoparticles

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Publication details

The article was received on 16 Jul 2010, accepted on 09 Sep 2010 and first published on 27 Sep 2010


Article type: Communication
DOI: 10.1039/C0CC02606A
Citation: Chem. Commun., 2010,46, 8011-8013
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    Cooperative spin crossover phenomena in [Fe(NH2trz)3](tosylate)2 nanoparticles

    A. Tokarev, L. Salmon, Y. Guari, W. Nicolazzi, G. Molnár and A. Bousseksou, Chem. Commun., 2010, 46, 8011
    DOI: 10.1039/C0CC02606A

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