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Issue 47, 2010
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Development of the first well-defined tungsten oxo alkyl derivatives supported on silica by SOMC: towards a model of WO3/SiO2 olefin metathesiscatalyst

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Abstract

A well-defined, silica-supported tungsten oxo alkyl species prepared by the surface organometallic chemistry approach displays high and sustained activity in propene metathesis. Remarkably, its catalytic performances outpace those of the parent imido derivative, underlining the importance of the oxo ligand in the design of robust catalysts.

Graphical abstract: Development of the first well-defined tungsten oxo alkyl derivatives supported on silica by SOMC: towards a model of WO3/SiO2 olefin metathesis catalyst

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Article information


Submitted
12 Jul 2010
Accepted
13 Oct 2010
First published
27 Oct 2010

Chem. Commun., 2010,46, 8944-8946
Article type
Communication

Development of the first well-defined tungsten oxo alkyl derivatives supported on silica by SOMC: towards a model of WO3/SiO2 olefin metathesis catalyst

E. Mazoyer, N. Merle, A. D. Mallmann, J. Basset, E. Berrier, L. Delevoye, J. Paul, C. P. Nicholas, R. M. Gauvin and M. Taoufik, Chem. Commun., 2010, 46, 8944
DOI: 10.1039/C0CC02507K

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