Jump to main content
Jump to site search

Issue 40, 2010
Previous Article Next Article

Substantial exchange coupling for {Mo–NCS–M} combination: illustration for 1-D [{Mo(NCS)6}{NiL}2(NCS)]n

Author affiliations

Abstract

An antiferromagnetic interaction of J = −51 cm−1 has been obtained in a NCS-bridged {MoIIINi} compound (i.e. [{Mo(NCS)6}{NiL}2(NCS)]n), a value twice as large as for the homologous {CrIIINi} derivative. The DFT calculated spin distribution on {Mo(NCS)6}3 reveals noticeable spin on the S atoms.

Graphical abstract: Substantial exchange coupling for {Mo–NCS–M} combination: illustration for 1-D [{Mo(NCS)6}{NiL}2(NCS)]n

Back to tab navigation

Supplementary files

Publication details

The article was received on 11 Jul 2010, accepted on 27 Aug 2010 and first published on 10 Sep 2010


Article type: Communication
DOI: 10.1039/C0CC02498H
Citation: Chem. Commun., 2010,46, 7519-7521
  •   Request permissions

    Substantial exchange coupling for {Mo–NCS–M} combination: illustration for 1-D [{Mo(NCS)6}{NiL}2(NCS)]n

    M. Mousavi, V. Béreau, C. Desplanches, C. Duhayon and J. Sutter, Chem. Commun., 2010, 46, 7519
    DOI: 10.1039/C0CC02498H

Search articles by author

Spotlight

Advertisements