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Issue 40, 2010
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Development of 5-silylethynyl-1,3-dioxolan-4-one as a new prochiral template for asymmetric phase-transfer catalysis

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Abstract

Phase-transfer catalyzed asymmetric alkylation and Michael addition of 5-silylalkynyl-1,3-dioxolan-4-one were developed as a novel strategy to provide highly modular tertiary α-alkyl-α-hydroxy acids bearing an alkyne moiety.

Graphical abstract: Development of 5-silylethynyl-1,3-dioxolan-4-one as a new prochiral template for asymmetric phase-transfer catalysis

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Publication details

The article was received on 02 Jul 2010, accepted on 23 Aug 2010 and first published on 10 Sep 2010


Article type: Communication
DOI: 10.1039/C0CC02334E
Citation: Chem. Commun., 2010,46, 7593-7595

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    Development of 5-silylethynyl-1,3-dioxolan-4-one as a new prochiral template for asymmetric phase-transfer catalysis

    T. Hashimoto, K. Fukumoto, N. Abe, K. Sakata and K. Maruoka, Chem. Commun., 2010, 46, 7593
    DOI: 10.1039/C0CC02334E

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