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Issue 31, 2010
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Parahydrogen-induced polarization in alkyne hydrogenation catalyzed by Pd nanoparticles embedded in a supported ionic liquid phase

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Abstract

Parahydrogen-induced polarization was observed in the gas phase heterogeneous hydrogenation of propyne catalyzed by Pd0 nanoparticles embedded in an ionic liquid phase supported on activated carbon fibers (Pd0/SILP/ACF). The results were markedly different from those obtained with a reference catalyst, Pd0/ACF, demonstrating the important role of the ionic liquid.

Graphical abstract: Parahydrogen-induced polarization in alkyne hydrogenation catalyzed by Pd nanoparticles embedded in a supported ionic liquid phase

  • This article is part of the themed collection: Hydrogen
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Publication details

The article was received on 14 May 2010, accepted on 22 Jun 2010 and first published on 06 Jul 2010


Article type: Communication
DOI: 10.1039/C0CC01411G
Citation: Chem. Commun., 2010,46, 5764-5766
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    Parahydrogen-induced polarization in alkyne hydrogenation catalyzed by Pd nanoparticles embedded in a supported ionic liquid phase

    K. V. Kovtunov, V. V. Zhivonitko, L. Kiwi-Minsker and I. V. Koptyug, Chem. Commun., 2010, 46, 5764
    DOI: 10.1039/C0CC01411G

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