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Issue 27, 2010
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Transannular, decarboxylative Claisen rearrangement reactions for the synthesis of sulfur-substituted vinylcyclopropanes

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Abstract

Unsaturated ε-lactones bearing an α-arylsulfonyl or α-arylsulfoximinyl substituent undergo stereoselective transannular, decarboxylative Claisen rearrangement to give substituted vinylcyclopropanes.

Graphical abstract: Transannular, decarboxylative Claisen rearrangement reactions for the synthesis of sulfur-substituted vinylcyclopropanes

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Publication details

The article was received on 16 Apr 2010, accepted on 12 May 2010 and first published on 01 Jun 2010


Article type: Communication
DOI: 10.1039/C0CC00976H
Citation: Chem. Commun., 2010,46, 4991-4993
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    Transannular, decarboxylative Claisen rearrangement reactions for the synthesis of sulfur-substituted vinylcyclopropanes

    D. Craig, S. J. Gore, M. I. Lansdell, S. E. Lewis, A. V. W. Mayweg and A. J. P. White, Chem. Commun., 2010, 46, 4991
    DOI: 10.1039/C0CC00976H

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