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Issue 26, 2010
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Glycosylation with glycosyl N-phenyltrifluoroacetimidates (PTFAI) and a perspective of the future development of new glycosylation methods

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Abstract

The glycosyl N-phenyltrifluoroacetimidates (PTFAI) have within the last ten years been applied in the synthesis of a wide variety of the oligosaccharides and glycoconjugates. Especially, these donors are found advantageous in glycosidic coupling with ‘arming’ sugar donors, ketose donors, and with less nucleophilic acceptors. A comprehensive review of the PTFAI donors is provided in a hope to reflect from a particular angle the current status and future trend of the glycosylation chemistry.

Graphical abstract: Glycosylation with glycosyl N-phenyltrifluoroacetimidates (PTFAI) and a perspective of the future development of new glycosylation methods

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Publication details

The article was received on 24 Mar 2010, accepted on 13 Apr 2010 and first published on 26 May 2010


Article type: Feature Article
DOI: 10.1039/C0CC00563K
Citation: Chem. Commun., 2010,46, 4668-4679

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    Glycosylation with glycosyl N-phenyltrifluoroacetimidates (PTFAI) and a perspective of the future development of new glycosylation methods

    B. Yu and J. Sun, Chem. Commun., 2010, 46, 4668
    DOI: 10.1039/C0CC00563K

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