Issue 32, 2010
From the journal:

Chemical Communications

Olefinepoxidation by hydrogen peroxide catalysed by molybdenum complexes in ionic liquids and structural characterisation of the proposed intermediate dioxoperoxomolybdenum species†

Matthew Herbert,a   Eleuterio Álvarez,b   David J. Cole-Hamilton,c   Francisco Montilla*a  and  Agustín Galindo*a  

* Corresponding authors

a Departamento de Química Inorgánica, Facultad de Química, Universidad de Sevilla, Aptdo 1203, 41071 Sevilla, Spain
E-mail: galindo@us.es, montilla@us.es
Fax: + 34 954 557153

b Instituto de Investigaciones Químicas, CSIC-Universidad de Sevilla, Avda. Américo Vespucio 49, 41092 Sevilla, Spain

c School of Chemistry, University of St Andrews, North Haugh, St Andrews, UK

Abstract

The complex [Mo4O16(dmpz)6] (1) has been isolated as part of a study of oxodiperoxomolybdenum catalysed epoxidation of olefin substrates with hydrogen peroxide in ionic liquids. Notably, 1 is the first dioxoperoxomolybdenum species to be structurally characterised.

Graphical abstract: Olefin epoxidation by hydrogen peroxide catalysed by molybdenum complexes in ionic liquids and structural characterisation of the proposed intermediate dioxoperoxomolybdenum species

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Article information

DOI
https://doi.org/10.1039/C0CC00462F
Article type
Communication
Submitted
18 Mar 2010
Accepted
15 Jun 2010
First published
02 Jul 2010

Chem. Commun., 2010,46, 5933-5935

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Olefin epoxidation by hydrogen peroxide catalysed by molybdenum complexes in ionic liquids and structural characterisation of the proposed intermediate dioxoperoxomolybdenum species

M. Herbert, E. Álvarez, D. J. Cole-Hamilton, F. Montilla and A. Galindo, Chem. Commun., 2010, 46, 5933 DOI: 10.1039/C0CC00462F

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