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Issue 28, 2010
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Synthesis and characterisation of the persistent radical [BCl2(bipy)]˙

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Abstract

The persistent radical, [BCl2(bipy)]˙ (bipy = 2,2′-bipyridyl), has been prepared and characterised by X-ray crystallography, ESR and DFT calculations. The structure is compared with that of the cation, [BCl2(bipy)]+.

Graphical abstract: Synthesis and characterisation of the persistent radical [BCl2(bipy)]˙

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Publication details

The article was received on 02 Mar 2010, accepted on 27 Apr 2010 and first published on 16 Jun 2010


Article type: Communication
DOI: 10.1039/C0CC00187B
Citation: Chem. Commun., 2010,46, 5070-5072

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    Synthesis and characterisation of the persistent radical [BCl2(bipy)]˙

    S. M. Mansell, C. J. Adams, G. Bramham, M. F. Haddow, W. Kaim, N. C. Norman, J. E. McGrady, C. A. Russell and S. J. Udeen, Chem. Commun., 2010, 46, 5070
    DOI: 10.1039/C0CC00187B

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