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Issue 23, 2010
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Silica gel-mediated rearrangement of allylic acetates. Application to the synthesis of 1,3-enynes

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Abstract

Silica gel was found to efficiently promote the rearrangement of allylic acetates into their most stable regioisomers under microwave irradiation. The reaction is easy to perform and eco-friendly. This method was applied to the metal-free synthesis of 1,3-enynes.

Graphical abstract: Silica gel-mediated rearrangement of allylic acetates. Application to the synthesis of 1,3-enynes

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Article information


Submitted
19 Feb 2010
Accepted
09 Apr 2010
First published
12 May 2010

Chem. Commun., 2010,46, 4178-4180
Article type
Communication

Silica gel-mediated rearrangement of allylic acetates. Application to the synthesis of 1,3-enynes

A. Serra-Muns, A. Guérinot, S. Reymond and J. Cossy, Chem. Commun., 2010, 46, 4178
DOI: 10.1039/C0CC00035C

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