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Issue 17, 2010
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Oxygen and protonreduction by decamethylferrocene in non-aqueous acidic media

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Abstract

Experimental studies and density functional theory (DFT) computations suggest that oxygen and proton reduction by decamethylferrocene (DMFc) in 1,2-dichloroethane involves protonated DMFc, DMFcH+, as an active intermediate species, producing hydrogen peroxide and hydrogen in aerobic and anaerobic conditions, respectively.

Graphical abstract: Oxygen and proton reduction by decamethylferrocene in non-aqueous acidic media

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Article information


Submitted
18 Jan 2010
Accepted
03 Mar 2010
First published
18 Mar 2010

Chem. Commun., 2010,46, 2918-2919
Article type
Communication

Oxygen and proton reduction by decamethylferrocene in non-aqueous acidic media

B. Su, I. Hatay, P. Y. Ge, M. Mendez, C. Corminboeuf, Z. Samec, M. Ersoz and H. H. Girault, Chem. Commun., 2010, 46, 2918
DOI: 10.1039/B926963K

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