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Issue 12, 2010
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Site-specific pKa determination of the carboxylate-binding subunit in artificial peptide receptors

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Abstract

Site-specific pKa determination of the carboxylate-binding subunit in artificial peptide receptors is achieved by pH-dependent UV resonance Raman scattering with subsequent matrix factorization. This quantitative methodology allows to determine accurately the local acidity of a binding site based on the complete vibrational spectrum and, most importantly, without the need of selecting any particular peak.

Graphical abstract: Site-specific pKa determination of the carboxylate-binding subunit in artificial peptide receptors

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Publication details

The article was received on 15 Dec 2009, accepted on 01 Feb 2010 and first published on 17 Feb 2010


Article type: Communication
DOI: 10.1039/B926514G
Citation: Chem. Commun., 2010,46, 2133-2135

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    Site-specific pKa determination of the carboxylate-binding subunit in artificial peptide receptors

    S. Niebling, S. K. Srivastava, C. Herrmann, P. R. Wich, C. Schmuck and S. Schlücker, Chem. Commun., 2010, 46, 2133
    DOI: 10.1039/B926514G

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