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Issue 11, 2010
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Spin capturing with nitrones: radical coupling reactions with concurrent introduction of mid-chain functionality†

Edgar H. H. Wong,ab   Cyrille Boyer,b   Martina H. Stenzel,b   Christopher Barner-Kowollik*a  and  Thomas Junkers*a  
Author affiliations

* Corresponding authors

a Preparative Macromolecular Chemistry, Institut für Technische Chemie und Polymerchemie, Karlsruhe Institute of Technology (KIT), Engesserstr. 18, Geb. 11.23, 76128 Karlsruhe, Germany
E-mail: christopher.barner-kowollik@kit.edu, thomas.junkers@kit.edu
Web: www.macroarc.de
Fax: (+49)721-6085740
Tel: (+49)721-6085641

b Centre for Advanced Macromolecular Design (CAMD), School of Chemical Sciences and Engineering, The University of New South Wales, Sydney, Australia
Web: www.camd.unsw.edu.au

Abstract

Nitrones are demonstrated to efficiently mediate radical coupling reactions on the example of the conjugation of ATRP-made polymers, yielding macromolecules with distinct functional alkoxyamine centres in mid-chain locations of the chains.

Graphical abstract: Spin capturing with nitrones: radical coupling reactions with concurrent introduction of mid-chain functionality

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Article information

Submitted
02 Dec 2009
Accepted
21 Dec 2009
First published
14 Jan 2010
Chem. Commun., 2010,46, 1959-1961
Article type
Communication
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Spin capturing with nitrones: radical coupling reactions with concurrent introduction of mid-chain functionality

E. H. H. Wong, C. Boyer, M. H. Stenzel, C. Barner-Kowollik and T. Junkers, Chem. Commun., 2010, 46, 1959
DOI: 10.1039/B925390D

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