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Issue 6, 2010
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An early–late heterobimetallic complex with an unsupported dative bond: synthesis and structure of [(Cy3P)2PtZrCl4]

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Abstract

The presented platinum zirconium adduct [(Cy3P)2PtZrCl4] expands the range of known platinum metal adducts towards early–late heterobimetallics displaying the first unsupported dative transition metal bond; X-ray structure and DFT calculations gave an estimation about the bond strength and indicate a strong Pt–Zr bond.

Graphical abstract: An early–late heterobimetallic complex with an unsupported dative bond: synthesis and structure of [(Cy3P)2Pt–ZrCl4]

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Publication details

The article was received on 15 Oct 2009, accepted on 17 Nov 2009 and first published on 07 Dec 2009


Article type: Communication
DOI: 10.1039/B921608A
Citation: Chem. Commun., 2010,46, 913-915

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    An early–late heterobimetallic complex with an unsupported dative bond: synthesis and structure of [(Cy3P)2PtZrCl4]

    H. Braunschweig, K. Radacki and K. Schwab, Chem. Commun., 2010, 46, 913
    DOI: 10.1039/B921608A

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