Unique ZnII coordination entanglement networks with a flexible fluorinated bis-pyridinecarboxamide tecton and benzenedicarboxylates

Zhi-Hui Zhang; Sheng-Chun Chen; Jin-Ling Mi; Ming-Yang He; Qun Chen; Miao Du

doi:10.1039/C0CC03173A

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Unique Zn^II coordination entanglement networks with a flexible fluorinated bis-pyridinecarboxamide tecton and benzenedicarboxylates†

Zhi-Hui Zhang,^a Sheng-Chun Chen,^a Jin-Ling Mi,^a Ming-Yang He,^a Qun Chen*^a and Miao Du*^b

Author affiliations

* Corresponding authors

^a Key Laboratory of Fine Petrochemical Technology, Changzhou University, Changzhou 213164, P. R. China
E-mail: chenqunjpu@yahoo.com

^b College of Chemistry, Tianjin Key Laboratory of Structureand Performance for Functional Molecule, Tianjin Normal University, Tianjin 300387, P. R. China
E-mail: dumiao@public.tpt.tj.cn

Abstract

Entangled nets in coordination compounds with both self-penetrating and interpenetrating structural features have been first constructed by using a flexible bis-pyridinecarboxamide and isophthalate or 5-methylisophthalate. Distinct entangled systems showing both 3-fold interpenetration and polyrotaxane can also be obtained by altering the 5-substituents of isophthalate.

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Article information

DOI: https://doi.org/10.1039/C0CC03173A
Article type: Communication
Submitted: 11 Aug 2010
Accepted: 24 Sep 2010
First published: 11 Oct 2010

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Chem. Commun., 2010,46, 8427-8429

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Unique Zn^II coordination entanglement networks with a flexible fluorinated bis-pyridinecarboxamide tecton and benzenedicarboxylates

Z. Zhang, S. Chen, J. Mi, M. He, Q. Chen and M. Du, Chem. Commun., 2010, 46, 8427 DOI: 10.1039/C0CC03173A

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Chemical Communications