Issue 39, 2010
From the journal:

Chemical Communications

The first supraicosahedral bis(heteroborane)†

David Ellis,*a   Georgina M. Rosaira  and  Alan J. Welch*a  

* Corresponding authors

a Department of Chemistry, Heriot-Watt University, Edinburgh, UK
E-mail: a.j.welch@hw.ac.uk
Fax: +44 (0)131 3180
Tel: +44 (0)131 3217

Abstract

The first supraicosahedral bis(heteroborane), 1-(4′-Cp-4′,1′,6′-closo-CoC2B10H11)-4-Cp-4,1,6-closo-CoC2B10H11 has been synthesised as a mixture of racemic and meso diastereoisomers. Analysis of the molecular structures reveals clear evidence of internally crowded molecules.

Graphical abstract: The first supraicosahedral bis(heteroborane)

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Article information

DOI
https://doi.org/10.1039/C0CC02534H
Article type
Communication
Submitted
13 Jul 2010
Accepted
19 Aug 2010
First published
07 Sep 2010

Chem. Commun., 2010,46, 7394-7396

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The first supraicosahedral bis(heteroborane)

D. Ellis, G. M. Rosair and A. J. Welch, Chem. Commun., 2010, 46, 7394 DOI: 10.1039/C0CC02534H

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