Issue 40, 2010

Substantial exchange coupling for {Mo–NCS–M} combination: illustration for 1-D [{Mo(NCS)6}{NiL}2(NCS)]n

Abstract

An antiferromagnetic interaction of J = −51 cm−1 has been obtained in a NCS-bridged {MoIIINi} compound (i.e. [{Mo(NCS)6}{NiL}2(NCS)]n), a value twice as large as for the homologous {CrIIINi} derivative. The DFT calculated spin distribution on {Mo(NCS)6}3 reveals noticeable spin on the S atoms.

Graphical abstract: Substantial exchange coupling for {Mo–NCS–M} combination: illustration for 1-D [{Mo(NCS)6}{NiL}2(NCS)]n

Supplementary files

Article information

Article type
Communication
Submitted
11 Jul 2010
Accepted
27 Aug 2010
First published
10 Sep 2010

Chem. Commun., 2010,46, 7519-7521

Substantial exchange coupling for {Mo–NCS–M} combination: illustration for 1-D [{Mo(NCS)6}{NiL}2(NCS)]n

M. Mousavi, V. Béreau, C. Desplanches, C. Duhayon and J. Sutter, Chem. Commun., 2010, 46, 7519 DOI: 10.1039/C0CC02498H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements