Issue 36, 2010
From the journal:

Chemical Communications

Catalytic intramolecular aromatic C–H alkenylation of arenes with non-activated ketones: synthesis of 4-alkylene quinolin-2-ones†

Yeming Wang,a   Wei-Qi Li,b   Guangbo Che,c   Xihe Bi,*a   Peiqiu Liao,a   Qian Zhanga  and  Qun Liu*a  

* Corresponding authors

a Department of Chemistry, Northeast Normal University, Changchun, 130024, China
E-mail: bixh507@nenu.edu.cn, liuqun@nenu.edu.cn
Fax: (+86) 431-8509-9759
Tel: (+86) 431-8509-9759

b Physical Department, Harbin Institute of Technology, No. 92, West Da-Zhi Street, Harbin 150001, PR China

c Key Laboratory of Preparation and Applications of Environmental Friendly Materials (Jilin Normal University), Chinese Ministry of Education, Siping 136000, PR China

Abstract

The catalytic intramolecular aromatic C–H alkenylation of arenes with non-activated ketone carbonyls has been realized for the first time, leading to the synthesis of antiviral 4-alkylene quinolin-2-ones, where the quaternary carbon adjacent to the ketone carbonyl plays an essential role in this catalytic reaction.

Graphical abstract: Catalytic intramolecular aromatic C–H alkenylation of arenes with non-activated ketones: synthesis of 4-alkylene quinolin-2-ones

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Article information

DOI
https://doi.org/10.1039/C0CC01758B
Article type
Communication
Submitted
05 Jun 2010
Accepted
28 Jul 2010
First published
25 Aug 2010

Chem. Commun., 2010,46, 6843-6845

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Catalytic intramolecular aromatic C–H alkenylation of arenes with non-activated ketones: synthesis of 4-alkylene quinolin-2-ones

Y. Wang, W. Li, G. Che, X. Bi, P. Liao, Q. Zhang and Q. Liu, Chem. Commun., 2010, 46, 6843 DOI: 10.1039/C0CC01758B

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