Issue 35, 2010
From the journal:

Chemical Communications

Selective polymerization of polypyrrole in silica mesopores using an in situ generated oxidizing agent on a silica surface†

Yongju Jung,ab   Ryan L. Spray,a   Jin Hoe Kim,c   Ji Man Kimc  and  Kyoung-Shin Choi*a  

* Corresponding authors

a Department of Chemistry, Purdue University, West Lafayette, USA
E-mail: kchoi1@purdue.edu
Fax: +1 765 494 0239
Tel: +1 765 494 0049

b Department of Applied Chemical Engineering, Korea University of Technology and Education, Cheonan 330-708, Korea

c Department of Chemistry, BK21 School of Chemical Materials Science and Department of Energy Science, Sungkyunkwan University, Suwon 440-746, Korea

Abstract

A novel method that selectively polymerizes pyrrole on the silica surface without inducing polymerization in bulk solution is developed, which is based on in situ generation of the NO+ ion as an oxidant at the silica surface.

Graphical abstract: Selective polymerization of polypyrrole in silica mesopores using an in situ generated oxidizing agent on a silica surface

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Article information

DOI
https://doi.org/10.1039/C0CC01746A
Article type
Communication
Submitted
04 Jun 2010
Accepted
16 Jul 2010
First published
16 Aug 2010

Chem. Commun., 2010,46, 6566-6568

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Selective polymerization of polypyrrole in silica mesopores using an in situ generated oxidizing agent on a silica surface

Y. Jung, R. L. Spray, J. H. Kim, J. M. Kim and K. Choi, Chem. Commun., 2010, 46, 6566 DOI: 10.1039/C0CC01746A

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