Issue 38, 2010
From the journal:

Chemical Communications

Reactions of a β-diketiminate zinc hydride complex with heterocumulenes†

Stephan Schulz,*a   Tamara Eisenmann,a   Sarah Schmidt,a   Dieter Bläser,a   Ulrich Westphala  and  Roland Boesea  

* Corresponding authors

a University of Duisburg-Essen, Universitätsstr. 5-7, S07 S03 C30, 45117 Essen, Germany
E-mail: stephan.schulz@uni-due.de
Fax: +49 201 1833830
Tel: +49 201 1834635

Abstract

The β-diketiminate zinc hydride MesnacnacZnH (1) reacts with CO2, C(Ni-Pr)2 and t-BuNCO at ambient temperature with insertion into the Zn–H bond and subsequent formation of the corresponding formato (2), formamido (3) and formamidinato (4) complexes.

Graphical abstract: Reactions of a β-diketiminate zinc hydride complex with heterocumulenes

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Article information

DOI
https://doi.org/10.1039/C0CC01329C
Article type
Communication
Submitted
10 May 2010
Accepted
21 Jul 2010
First published
01 Sep 2010

Chem. Commun., 2010,46, 7226-7228

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Reactions of a β-diketiminate zinc hydride complex with heterocumulenes

S. Schulz, T. Eisenmann, S. Schmidt, D. Bläser, U. Westphal and R. Boese, Chem. Commun., 2010, 46, 7226 DOI: 10.1039/C0CC01329C

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