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Issue 38, 2010
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Reactions of a β-diketiminate zinc hydride complex with heterocumulenes

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Abstract

The β-diketiminate zinc hydride MesnacnacZnH (1) reacts with CO2, C(Ni-Pr)2 and t-BuNCO at ambient temperature with insertion into the Zn–H bond and subsequent formation of the corresponding formato (2), formamido (3) and formamidinato (4) complexes.

Graphical abstract: Reactions of a β-diketiminate zinc hydride complex with heterocumulenes

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Article information


Submitted
10 May 2010
Accepted
21 Jul 2010
First published
01 Sep 2010

Chem. Commun., 2010,46, 7226-7228
Article type
Communication

Reactions of a β-diketiminate zinc hydride complex with heterocumulenes

S. Schulz, T. Eisenmann, S. Schmidt, D. Bläser, U. Westphal and R. Boese, Chem. Commun., 2010, 46, 7226
DOI: 10.1039/C0CC01329C

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