Issue 33, 2010
From the journal:

Chemical Communications

Synthesis and characterisation of 3,4-dialkoxy-substituted benzo-1,3,2-dithiazolyl radicals†

Antonio Alberola,a   Dana Eisler,a   Robert J. Less,a   Efren Navarro-Moratallaa  and  Jeremy M. Rawson*a  

* Corresponding authors

a Department of Chemistry, The University of Cambridge, Lensfield Road, Cambridge CB2 1EW, UK
E-mail: jmr31@cam.ac.uk

Abstract

The conversion of 3,4-dialkoxy-benzenes into dialkoxy-benzo-1,3,2-dithiazolyls is described and representative examples (1 and 2) derived from benzodioxole and veratrol, respectively, are reported. Whilst 1 is a dimeric π*–π* dimer, the dimethoxy derivative 2 is monomeric in the solid state and exhibits antiferromagnetic interactions.

Graphical abstract: Synthesis and characterisation of 3,4-dialkoxy-substituted benzo-1,3,2-dithiazolyl radicals

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Article information

DOI
https://doi.org/10.1039/C0CC01282C
Article type
Communication
Submitted
07 May 2010
Accepted
25 Jun 2010
First published
26 Jul 2010

Chem. Commun., 2010,46, 6114-6116

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Synthesis and characterisation of 3,4-dialkoxy-substituted benzo-1,3,2-dithiazolyl radicals

A. Alberola, D. Eisler, R. J. Less, E. Navarro-Moratalla and J. M. Rawson, Chem. Commun., 2010, 46, 6114 DOI: 10.1039/C0CC01282C

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