Issue 27, 2010
From the journal:

Chemical Communications

Stereospecific and quantitative photodimerisation of terminal olefins in the solid state†

Ivan G. Georgiev,‡a   Dejan-Krešimir Bučar‡a  and  Leonard R. MacGillivray*a  

* Corresponding authors

a Department of Chemistry, University of Iowa, Iowa City, USA
E-mail: len-macgillivray@uiowa.edu
Fax: +1 319-335-1270
Tel: +1 319-335-0563

Abstract

Reaction of 4-vinylpyridine with AgClO3 yields a crystalline solid that supports a stereospecific and quantitative [2+2] photodimerisation of two terminal olefins. Structural dynamics of the −CH[double bond, length as m-dash]CH2 group, nature of the counterion, and extended packing influence the photoreactivity.

Graphical abstract: Stereospecific and quantitative photodimerisation of terminal olefins in the solid state

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Article information

DOI
https://doi.org/10.1039/C0CC01184C
Article type
Communication
Submitted
29 Apr 2010
Accepted
05 May 2010
First published
01 Jun 2010

Chem. Commun., 2010,46, 4956-4958

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Stereospecific and quantitative photodimerisation of terminal olefins in the solid state

I. G. Georgiev, D. Bučar and L. R. MacGillivray, Chem. Commun., 2010, 46, 4956 DOI: 10.1039/C0CC01184C

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