Issue 29, 2010
From the journal:

Chemical Communications

Conversion of nonporous helical cadmium organic framework to a porous form†

Zhi-Gang Gu,a   Yue-Peng Cai,*a   Hua-Cai Fang,a   Zheng-Yuan Zhou,a   Praveen K. Thallapally,*b   Jian Tian,b   Jun Liub  and  Gregory J. Exarhosb  

* Corresponding authors

a School of Chemistry and Environment, Key Lab of Technology on Electrochemical Energy Storage and Power Generation in Guangdong Universities, Engineering Research Center of Materials and Technology for Electrochemical EnergyStorage (Ministry of Education), South China Normal University, Guangzhou 510006

b Energy and Environment Directorate, Pacific Northwest National Laboratory, Richland, WA 99352 USA

Abstract

Two novel cadmium–organic frameworks containing achiral helical nanotubular channels, [Cd(HImDC)(S)]n (S = Im(1) and Py(2)), have been synthesized and characterized using single crystal X-ray diffraction, in which 1 converts to 2 upon refluxing 1 in pyridine solution with noticeable porosity and hydrogen uptake at medium pressure.

Graphical abstract: Conversion of nonporous helical cadmium organic framework to a porous form

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Article information

DOI
https://doi.org/10.1039/C0CC01042A
Article type
Communication
Submitted
21 Apr 2010
Accepted
02 Jun 2010
First published
22 Jun 2010

Chem. Commun., 2010,46, 5373-5375

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Conversion of nonporous helical cadmium organic framework to a porous form

Z. Gu, Y. Cai, H. Fang, Z. Zhou, P. K. Thallapally, J. Tian, J. Liu and G. J. Exarhos, Chem. Commun., 2010, 46, 5373 DOI: 10.1039/C0CC01042A

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