Issue 32, 2010
From the journal:

Chemical Communications

Monitoring the stepwise assembly of a 3-D framework from a supramolecular lanthanoid synthon by in situinfrared spectroscopy†

Philip C. Andrews,a   William J. Gee,a   Peter C. Junk,*a   Harald Krautscheidb  and  Jonathan G. MacLellana  

* Corresponding authors

a School of Chemistry, Monash University, Clayton, Melbourne, Australia
E-mail: Peter.Junk@sci.monash.edu.au
Fax: +61 (0)3-9905 4597
Tel: +61 (0)3-99054570

b Institut für Anorganische Chemie, Universität Leipzig, 04103 Leipzig, Germany

Abstract

Construction of a 3-D supramolecular network from [Ln(cpb)3(H2O)2] (Ln = Nd, Tb; Hcpb = 1-(4-cyanophenyl)-1,3-butanedione) by sequential displacement of a coordinated water by DMF, dimerisation by reciprocal hydrogen bonding in solution and π–π stacking and interdigitation of nitriles has been monitored by in situ fourier transform infrared spectroscopy.

Graphical abstract: Monitoring the stepwise assembly of a 3-D framework from a supramolecular lanthanoid synthon by in situ infrared spectroscopy

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Article information

DOI
https://doi.org/10.1039/C0CC00949K
Article type
Communication
Submitted
15 Apr 2010
Accepted
15 Jun 2010
First published
01 Jul 2010

Chem. Commun., 2010,46, 5948-5950

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Monitoring the stepwise assembly of a 3-D framework from a supramolecular lanthanoid synthon by in situ infrared spectroscopy

P. C. Andrews, W. J. Gee, P. C. Junk, H. Krautscheid and J. G. MacLellan, Chem. Commun., 2010, 46, 5948 DOI: 10.1039/C0CC00949K

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