Issue 27, 2010
From the journal:

Chemical Communications

Actinide tetracyanoplatinates: synthesis and structural characterization with uncharacteristic Th–NC coordination and thorium fluorescence†

Branson A. Maynard,a   Richard E. Sykora,b   Joel T. Maguec  and  Anne E. V. Gorden*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, Auburn University, 179 Chemistry Building, Auburn, USA
E-mail: gordeae@auburn.edu
Fax: +1 334 844-6959
Tel: +1 334 844-4043

b Department of Chemistry, University of South Alabama, Chemistry Building, Mobile, USA
E-mail: rsykora@jaguar1.usouthal.edu
Fax: +1 251 460-7359
Tel: +1 251 460-7422

c Department of Chemistry, Tulane University, 2015 Percival Stern Hall New Orleans, USA
Tel: +1 504-865-5573

Abstract

Here, we report the synthesis of three novel actinide tetracyanoplatinates (AnTCP, where An = Th, UO2 unit and TCP = [Pt(CN)4]2−) along with their unique fluorescence properties and structural characterization by single crystal X-ray diffraction.

Graphical abstract: Actinide tetracyanoplatinates: synthesis and structural characterization with uncharacteristic Th–NC coordination and thorium fluorescence

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Article information

DOI
https://doi.org/10.1039/C0CC00343C
Article type
Communication
Submitted
11 Mar 2010
Accepted
06 May 2010
First published
01 Jun 2010

Chem. Commun., 2010,46, 4944-4946

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Actinide tetracyanoplatinates: synthesis and structural characterization with uncharacteristic Th–NC coordination and thorium fluorescence

B. A. Maynard, R. E. Sykora, J. T. Mague and A. E. V. Gorden, Chem. Commun., 2010, 46, 4944 DOI: 10.1039/C0CC00343C

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