Issue 33, 2010
From the journal:

Chemical Communications

Isoprenepolymerization with aminopyridinato ligand supported rare-earth metal complexes. Switching of the regio- and stereoselectivity†

Yi Yang,ab   Kui Lv,ab   Lingfang Wang,ab   Yang Wangab  and  Dongmei Cui*a  

* Corresponding authors

a State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute ofApplied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
E-mail: dmcui@ciac.jl.cn
Fax: +86-431-85262773
Tel: +86-431-85262773

b Graduate University of Chinese Academy of Sciences, Beijing 100039, China

Abstract

The highly cis-1,4, trans-1,4 and 3,4-selective polymerizations of isoprene were successfully regulated by simply modifying the auxiliary ligands, metal centres and initiation groups of rare-earth metal complexes and cocatalysts.

Graphical abstract: Isoprene polymerization with aminopyridinato ligand supported rare-earth metal complexes. Switching of the regio- and stereoselectivity

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Article information

DOI
https://doi.org/10.1039/C0CC00297F
Article type
Communication
Submitted
09 Mar 2010
Accepted
18 Jun 2010
First published
12 Jul 2010

Chem. Commun., 2010,46, 6150-6152

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Isoprene polymerization with aminopyridinato ligand supported rare-earth metal complexes. Switching of the regio- and stereoselectivity

Y. Yang, K. Lv, L. Wang, Y. Wang and D. Cui, Chem. Commun., 2010, 46, 6150 DOI: 10.1039/C0CC00297F

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