Issue 29, 2010
From the journal:

Chemical Communications

Regioselective functionalization of alkanes by sequential dehydrogenation–hydrozirconation†

Yoichiro Kuninobu,*a   Tomonari Ureshino,a   Shun-ichi Yamamotoa  and  Kazuhiko Takai*a  

* Corresponding authors

a Division of Chemistry and Biochemistry, Graduate School of Natural Science and Technology, Okayama University, Tsushima, Kita-ku, Japan
E-mail: kuninobu@cc.okayama-u.ac.jp, ktakai@cc.okayama-u.ac.jp
Fax: +81 (0)86-251-8094
Tel: +81 (0)86-251-8095

Abstract

We have succeeded in formal regioselective functionalization of alkanes by iridium-catalyzed dehydrogenation, hydrozirconation of the resulting alkenes, and electrophilic reaction of the generated alkylzirconium intermediate.

Graphical abstract: Regioselective functionalization of alkanes by sequential dehydrogenation–hydrozirconation

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Article information

DOI
https://doi.org/10.1039/C0CC00243G
Article type
Communication
Submitted
05 Mar 2010
Accepted
01 Jun 2010
First published
14 Jun 2010

Chem. Commun., 2010,46, 5310-5312

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Regioselective functionalization of alkanes by sequential dehydrogenation–hydrozirconation

Y. Kuninobu, T. Ureshino, S. Yamamoto and K. Takai, Chem. Commun., 2010, 46, 5310 DOI: 10.1039/C0CC00243G

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