Issue 31, 2010
From the journal:

Chemical Communications

One electron organozinc ligands in metal rich molecules by Ga/Zn exchange: from Cp*Rh(GaCp*)2 to Cp*Rh(ZnR)4 units†

Mariusz Molon,a   Thomas Cadenbach,a   Timo Bollermann,a   Christian Gemela  and  Roland A. Fischer*a  

* Corresponding authors

a Anorganische Chemie II, Organometallics and Materials Chemistry, Ruhr-Universitaät Bochum, Universitätsstraße 150, 44780 Bochum, Germany
E-mail: Roland.Fischer@ruhr-uni-bochum.de
Fax: +49 (0)234 32-14174
Tel: +49 (0)234 32-24174

Abstract

Two unusual compounds, [{Cp*Rh(ZnCp*)2(ZnMe)(ZnCl)}2] (1) and [Cp*2Rh][(Cp*Rh)6Zn18Cl12(μ6-Cl)] (2), both bearing closed shell 18-electron square pyramidal Cp*RhZn4 building units were obtained by combined Ga/Zn, Me/Cp* and Me/Cl exchange upon treatment of [Cp*Rh(GaCp*)2(GaCl2Cp*)] with ZnMe2 (Cp* = pentamethylcyclopentadienyl).

Graphical abstract: One electron organozinc ligands in metal rich molecules by Ga/Zn exchange: from Cp*Rh(GaCp*)2 to Cp*Rh(ZnR)4 units

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Article information

DOI
https://doi.org/10.1039/C0CC00146E
Article type
Communication
Submitted
26 Feb 2010
Accepted
17 Jun 2010
First published
09 Jul 2010

Chem. Commun., 2010,46, 5677-5679

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One electron organozinc ligands in metal rich molecules by Ga/Zn exchange: from Cp*Rh(GaCp*)2 to Cp*Rh(ZnR)4 units

M. Molon, T. Cadenbach, T. Bollermann, C. Gemel and R. A. Fischer, Chem. Commun., 2010, 46, 5677 DOI: 10.1039/C0CC00146E

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