Issue 22, 2010
From the journal:

Chemical Communications

Highly efficient catalytic dehydrative S-allylation of thiols and thioic S-acids†

Shinji Tanaka,a   Prasun Kanti Pradhan,a   Yusuke Maegawaa  and  Masato Kitamura*a  

* Corresponding authors

a Research Center for Materials Science and the Department of Chemistry, Nagoya University, Chikusa, Nagoya 464-8602, Japan
E-mail: kitamura@os.rcms.nagoya-u.ac.jp
Fax: +81 52-789-2261

Abstract

A SH-selective allylation method using [CpRu(2-quinolinecarboxylato)(η3-C3H5)]PF6 has been realized in various solvents including aqueous media to give allyl sulfides and allyl S-thioates, demonstrating the potential applicability to lipopeptide chemistry.

Graphical abstract: Highly efficient catalytic dehydrative S-allylation of thiols and thioic S-acids

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Article information

DOI
https://doi.org/10.1039/C0CC00096E
Article type
Communication
Submitted
24 Feb 2010
Accepted
13 Apr 2010
First published
05 May 2010

Chem. Commun., 2010,46, 3996-3998

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Highly efficient catalytic dehydrative S-allylation of thiols and thioic S-acids

S. Tanaka, P. K. Pradhan, Y. Maegawa and M. Kitamura, Chem. Commun., 2010, 46, 3996 DOI: 10.1039/C0CC00096E

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