Issue 21, 2010
From the journal:

Chemical Communications

Secondary orbital interactions in the propagation steps of lipid peroxidation†

Di Hua  and  Derek A. Pratt*a  

* Corresponding authors

a Department of Chemistry, Queen's University, 90 Bader Crescent, Kingston, Ontario, Canada
E-mail: pratt@chem.queensu.ca
Fax: +1 613 533 6669
Tel: +1 613 533 3287

Abstract

Calculations on the propagation steps in the radical chain oxidation of lipids (H-atom abstraction, O2 addition) show that secondary orbital interactions play an important role in the structure and energetics of the transition states of these reactions.

Graphical abstract: Secondary orbital interactions in the propagation steps of lipid peroxidation

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Article information

DOI
https://doi.org/10.1039/C0CC00019A
Article type
Communication
Submitted
18 Feb 2010
Accepted
23 Mar 2010
First published
13 Apr 2010

Chem. Commun., 2010,46, 3711-3713

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Secondary orbital interactions in the propagation steps of lipid peroxidation

D. Hu and D. A. Pratt, Chem. Commun., 2010, 46, 3711 DOI: 10.1039/C0CC00019A

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