Issue 29, 2010
From the journal:

Chemical Communications

Amido-stabilized rare-earth metal mixed methyl methylidene complexes†

Melanie Zimmermann,a   Dorothea Rauschmaier,b   Klaus Eichele,b   Karl W. Törnroosa  and  Reiner Anwander*b  

* Corresponding authors

a Department of Chemistry, University of Bergen, Allégaten 41, 5007 Bergen, Norway

b Institut für Anorganische Chemie, Universität Tübingen, Auf der Morgenstelle 18, 72076 Tübingen, Germany
E-mail: reiner.anwander@uni-tuebingen.de
Fax: +49 7071 292436

Abstract

Donor(thf)-induced tetramethylaluminate cleavage of Ln(AlMe4)2(NSiMe3AriPr) as well as the reaction of (LnMe3)n (Ln = Y, Ho, Lu) with HNSiMe3AriPr in tetrahydrofuran affords unprecedented trinuclear rare-earth metal tetramethyl methylidene complexes which act as Schrock-type nucleophilic carbenes and methyl transfer agents.

Graphical abstract: Amido-stabilized rare-earth metal mixed methyl methylidene complexes

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Article information

DOI
https://doi.org/10.1039/C003206A
Article type
Communication
Submitted
16 Feb 2010
Accepted
09 Jun 2010
First published
23 Jun 2010

Chem. Commun., 2010,46, 5346-5348

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Amido-stabilized rare-earth metal mixed methyl methylidene complexes

M. Zimmermann, D. Rauschmaier, K. Eichele, K. W. Törnroos and R. Anwander, Chem. Commun., 2010, 46, 5346 DOI: 10.1039/C003206A

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