Issue 17, 2010
From the journal:

Chemical Communications

Aminopropyltriethoxysilane stabilized ruthenium(0) nanoclusters as an isolable and reusable heterogeneous catalyst for the dehydrogenation of dimethylamine–borane†

Mehmet Zahmakıran,abc   Mar Tristany,ab   Karine Philippot,*ab   Katia Fajerwerg,ab   Saim Özkarc  and  Bruno Chaudretab  

* Corresponding authors

a CNRS, LCC (Laboratoire de Chimie de Coordination), 205, route de Narbonne, F-31077 Toulouse, France
E-mail: karine.philippot@lcc-toulouse.fr

b Université de Toulouse, UPS, INPT, LCC, F-31077 Toulouse, France

c Department of Chemistry, Middle East Technical University, Ankara, Turkey

Abstract

The preparation of Ru(0) nanoclusters stabilized by 3-aminopropyltriethoxysilane and their characterization by a combination of complementary techniques are described. These new Ru(0) nanoclusters provide high activity and unprecedented reusability as a heterogeneous catalyst in the dehydrogenation of dimethylamine–borane.

Graphical abstract: Aminopropyltriethoxysilane stabilized ruthenium(0) nanoclusters as an isolable and reusable heterogeneous catalyst for the dehydrogenation of dimethylamine–borane

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Article information

DOI
https://doi.org/10.1039/C000419G
Article type
Communication
Submitted
08 Jan 2010
Accepted
12 Feb 2010
First published
10 Mar 2010

Chem. Commun., 2010,46, 2938-2940

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Aminopropyltriethoxysilane stabilized ruthenium(0) nanoclusters as an isolable and reusable heterogeneous catalyst for the dehydrogenation of dimethylamine–borane

M. Zahmakıran, M. Tristany, K. Philippot, K. Fajerwerg, S. Özkar and B. Chaudret, Chem. Commun., 2010, 46, 2938 DOI: 10.1039/C000419G

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