Issue 18, 2010
From the journal:

Chemical Communications

Highly selective conversion of nitrobenzenes using a simple reducing system combined with a trivalent indium salt and a hydrosilane†

Norio Sakai,*a   Kohji Fujii,a   Shinya Nabeshima,a   Reiko Ikedaa  and  Takeo Konakaharaa  

* Corresponding authors

a Department of Pure and Applied Chemistry, Faculty of Science and Technology, Tokyo University of Science (RIKADAI), Noda, Chiba, Japan
E-mail: sakachem@rs.noda.tus.ac.jp
Fax: +81-4 -7123-9890
Tel: +81-4-7122-1092

Abstract

Controlling the type of indium salt and hydrosilane enables a highly selective reduction of aromatic nitro compounds into three coupling compounds, azoxybenzenes, azobenzenes and diphenylhydrazines, and one reductive compound, anilines.

Graphical abstract: Highly selective conversion of nitrobenzenes using a simple reducing system combined with a trivalent indium salt and a hydrosilane

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Article information

DOI
https://doi.org/10.1039/C000383B
Article type
Communication
Submitted
07 Jan 2010
Accepted
13 Feb 2010
First published
10 Mar 2010

Chem. Commun., 2010,46, 3173-3175

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Highly selective conversion of nitrobenzenes using a simple reducing system combined with a trivalent indium salt and a hydrosilane

N. Sakai, K. Fujii, S. Nabeshima, R. Ikeda and T. Konakahara, Chem. Commun., 2010, 46, 3173 DOI: 10.1039/C000383B

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