Longstanding living polymerization of ethylene: substituent effect on bridging carbon of 2-pyridinemethanamine nickel catalysts

Shaobo Zai; Fengshou Liu; Haiyang Gao; Cong Li; Guiyu Zhou; Shan Cheng; Lihua Guo; Ling Zhang; Fangming Zhu; Qing Wu

doi:10.1039/C000176G

Longstanding living polymerization of ethylene: substituent effect on bridging carbon of 2-pyridinemethanamine nickelcatalysts†

Shaobo Zai,^ab Fengshou Liu,^a Haiyang Gao,*^a Cong Li,^a Guiyu Zhou,^a Shan Cheng,^a Lihua Guo,^a Ling Zhang,^a Fangming Zhu^a and Qing Wu*^ab

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^a DSAPM Lab, Institute of Polymer Science, School of Chemistry and Chemical Engineering, Sun Yat-Sen (Zhongshan) University, Guangzhou, China
E-mail: gaohy@mail.sysu.edu.cn, ceswuq@mail.sysu.edu.cn
Fax: +86-20-84114033
Tel: +86-20-84114033

^b PCFM Lab, OFCM Institute, Sun Yat-Sen (Zhongshan) University, Guangzhou, China

Abstract

Bulky 2-pyridinemethanamine nickel complex activated by MAO was used as a catalyst to conduct longstanding living ethylene polymerization under atmospheric pressure to produce branched polyethylene.

Chemical Communications

Longstanding living polymerization of ethylene: substituent effect on bridging carbon of 2-pyridinemethanamine nickelcatalysts†

Abstract

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Longstanding living polymerization of ethylene: substituent effect on bridging carbon of 2-pyridinemethanamine nickel catalysts

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