Issue 17, 2010
From the journal:

Chemical Communications

Photochemical isomerisation of boryl-substituted silole derivatives†‡

Juri Ugolotti,a   Gerald Kehr,a   Roland Fröhlich§a  and  Gerhard Erker*a  

* Corresponding authors

a Organisch-Chemisches Institut, Westfälische Wilhelms-Universität, Corrensstrasse 40, 48149 Münster, Germany
E-mail: erker@uni-muenster.de
Fax: +49 251 83 36503

Abstract

Bis(alkynyl)silanes (1a,b) react with bis(pentafluorophenyl)-borane to 3-boryl-2,5-bis(trimethylsilyl) substituted siloles 3a,b. Subsequent irradiation of 3 with Pyrex filtered UV light resulted in the complete conversion to the new 5-boryl-2,3-bis(trimethylsilyl) substituted siloles 4a,b.

Graphical abstract: Photochemical isomerisation of boryl-substituted silole derivatives

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B927221F
Article type
Communication
Submitted
23 Dec 2009
Accepted
04 Mar 2010
First published
25 Mar 2010

Chem. Commun., 2010,46, 3016-3018

Permissions

Request permissions

Photochemical isomerisation of boryl-substituted silole derivatives

J. Ugolotti, G. Kehr, R. Fröhlich and G. Erker, Chem. Commun., 2010, 46, 3016 DOI: 10.1039/B927221F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements