Formation of an heterochiral supramolecular cage by diastereomer self-discrimination: fluorescence enhancement and C60 sensing

Carlos Solano Arribas; Ola F. Wendt; Anders P. Sundin; Carl-Johan Carling; Ruiyao Wang; Robert P. Lemieux; Kenneth Wärnmark

doi:10.1039/B927030B

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Formation of an heterochiral supramolecular cage by diastereomer self-discrimination: fluorescence enhancement and C₆₀ sensing†

Carlos Solano Arribas,^a Ola F. Wendt,^a Anders P. Sundin,^a Carl-Johan Carling,^ab Ruiyao Wang,^b Robert P. Lemieux^b and Kenneth Wärnmark*^a

Author affiliations

* Corresponding authors

^a Organic Chemistry, Department of Chemistry, Lund University, P.O. Box 124, SE-221 00 Lund, Sweden
E-mail: kenneth.warnmark@organic.lu.se
Fax: +46 46-2228209
Tel: +46 46-222821

^b Department of Chemistry, Queen's University, Kingston, ON, Canada

Abstract

Diastereomer discrimination was observed in the formation of a metallomacrocycle from a racemic ligand based on Tröger's base. The metallomacrocycle exhibited a dramatic increase in fluorescence intensity compared to the ligand and its fluorescence was efficiently quenched by C₆₀.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/B927030B
Article type: Communication
Submitted: 23 Dec 2009
Accepted: 04 May 2010
First published: 17 May 2010

Download Citation

Chem. Commun., 2010,46, 4381-4383

Permissions

Request permissions

Formation of an heterochiral supramolecular cage by diastereomer self-discrimination: fluorescence enhancement and C₆₀ sensing

C. S. Arribas, O. F. Wendt, A. P. Sundin, C. Carling, R. Wang, R. P. Lemieux and K. Wärnmark, Chem. Commun., 2010, 46, 4381 DOI: 10.1039/B927030B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications