Issue 20, 2010
From the journal:

Chemical Communications

Confirmation by IR of the preferred conformations of CFTAesters in solution: a highly reliable criterion for the stereochemistry assignment of chiral alcohols†

Kenji Omata,*a   Kohsuke Kotani,a   Kuninobu Kabuto,a   Tomoya Fujiwarab  and  Yoshio Takeuchib  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aoba, Aramaki, Aoba-ku, Sendai, Japan
E-mail: omata@he.tohoku.ac.jp

b Graduate School of Medicine and Pharmaceutical Sciences for Research, University of Toyama, 2630 Sugitani, Toyama, Japan

Abstract

Direct confirmation of the preferred conformation of diastereomeric esters derived from a chiral secondary alcohol and a chiral derivatizing agent in solution, which is crucial for reliable NMR-based assignment of absolute stereochemistry of the alcohol, has been attained for the first time by examination of IR spectra of the CFTA esters.

Graphical abstract: Confirmation by IR of the preferred conformations of CFTA esters in solution: a highly reliable criterion for the stereochemistry assignment of chiral alcohols

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B926793J
Article type
Communication
Submitted
21 Dec 2009
Accepted
19 Mar 2010
First published
15 Apr 2010

Chem. Commun., 2010,46, 3610-3612

Permissions

Request permissions

Confirmation by IR of the preferred conformations of CFTA esters in solution: a highly reliable criterion for the stereochemistry assignment of chiral alcohols

K. Omata, K. Kotani, K. Kabuto, T. Fujiwara and Y. Takeuchi, Chem. Commun., 2010, 46, 3610 DOI: 10.1039/B926793J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements