Natural abundance solid-state 95Mo MAS NMR of MoS2 reveals precise 95Mo anisotropic parameters from its central and satellite transitions

Hans J. Jakobsen; Henrik Bildsøe; Jørgen Skibsted; Michael Brorson; Kjeld Schaumburg

doi:10.1039/B926699B

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Natural abundance solid-state ⁹⁵MoMAS NMR of MoS₂ reveals precise ⁹⁵Mo anisotropic parameters from its central and satellite transitions†

Hans J. Jakobsen,*^a Henrik Bildsøe,^a Jørgen Skibsted,^a Michael Brorson^b and Kjeld Schaumburg^c

Author affiliations

* Corresponding authors

^a Instrument Centre for Solid-State NMR Spectroscopy, Interdisciplinary Nanoscience Center (iNANO), Department of Chemistry, Aarhus University, DK-8000 Aarhus C, Denmark
E-mail: hja@chem.au.dk
Fax: +45 8619 6199
Tel: +45 8942 3842

^b Haldor Topsøe A/S, Nymøllevej 55, DK-2800 Lyngby, Denmark
E-mail: mib@topsoe.dk
Fax: +45 4527 2999
Tel: +45 4527 2653

^c CISMI, Roskilde University, Universitetsvej 1, DK-4000 Roskilde, Denmark
E-mail: ksch@ruc.dk
Fax: +45 4674 3010
Tel: +45 4674 2533

Abstract

Precise values are reported for a quite large ⁹⁵Mo quadrupole coupling and an unusually large ⁹⁵Mo chemical shift anisotropy in MoS₂, values that have been retrieved by analysis of a well-resolved, highly complex 14.1 T ⁹⁵Mo MAS NMR spectrum displaying both the central and satellite transitions.

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Supplementary files

Experimental details, ⁹⁵Mo MAS NMR spectroscopy, definition of spectral parameters and STARS simulations, spectral simulations PDF (1117K)

Article information

DOI: https://doi.org/10.1039/B926699B
Article type: Communication
Submitted: 17 Dec 2009
Accepted: 22 Jan 2010
First published: 09 Feb 2010

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Chem. Commun., 2010,46, 2103-2105

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Natural abundance solid-state ⁹⁵Mo MAS NMR of MoS₂ reveals precise ⁹⁵Mo anisotropic parameters from its central and satellite transitions

H. J. Jakobsen, H. Bildsøe, J. Skibsted, M. Brorson and K. Schaumburg, Chem. Commun., 2010, 46, 2103 DOI: 10.1039/B926699B

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